1994 Audi 100 just sent all of the water out of the cooling system
As you have the heater core by-passed..you need to bleed the air from the by-pass hose..which can be fiddly..loosen a hose clamp and get the air out of the engine block..Audi 2.8 12v engines are tough to bleed sometimes...it mat take a couple of attempts.
See the link:quattroworld.com Forums: Bleeding the cooling system
After a while the thermostat finally opens and dumps coolant into the block..which is very hot due to air..and the coolant immediately boils..and you hear "thunks" as the boiling coolant expands..and the steam (which expands with terrific force) blows out of the block
Caps are cheap enough if there is any doubt
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I immediately let off the gas and coasted down an off-ramp, gingerly drove around a corner and parked at a gas station (maybe 1/4 mile extra distance from the venting location). The temp gauge rose steadily the whole time and just approached the over-temp warning area when I shut it down. As I recall, when we drained the system to repair it, there couldn't have been more than about 10-20% of the spec amount remaining.
I'd got the car with service history from the previous owner, and it listed standard services including a periodic replacement of the failed hose. But, its rotted condition told me that the mechanic had gotten lazy and checked it off without actually replacing it. That engine bay was pretty easy to get around in, except those hoses to the firewall were very hard to reach. Lots of scrambling around and improvising to get the corroded old hose clamps and rotted hose off those fittings...
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