Should my coolant boil?
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PV=nRT (http://en.wikipedia.org/wiki/Ideal_gas_law)
Pressure * Volume = number of moles * Universal Gas Constant * Temperature
If you lower the pressure then something else must change: the volume, the temperature or both.
Yes this is a law for the gasses, our boiling coolant is on the point to get to a gas so we can understand what's going on with this law.
I had this happening with my '89 Jetta even at operating temperature, only the action of opening the cap got the coolant to boil. This is why they recommend never opening the cap when the engine is hot, overheating or not.
BTW my explanations are probably not the most accurate of them all but it is only to explain a bit the idea.
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Things to consider:
Blocked radiator-maybe flush it?
Head gasket leaking letting air in the system from the cylinders.
Faulty x-tank cap-even though it's new, it could have been a defective one in the first place.
If you haven't yet done it, replace the MFTS. It's easy, and it will give you an accurate reading of your coolant temp(these can go bad and mislead you). Also, replace your fan switch (in the bottom right of the rad) to make sure your electric fan will operate when it's supposed to.
Viscous coupling-if your motor is hot, you should hear your fan(not electric) moving air, especially if the window is down.
Sorry to load you with stuff to think about here. I'd start with the easy stuff, and go from there.
HTH





